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Soil pollution

Wheat field
Source: domena publiczna.

Link to the lesson

Before you start you should know
  • what a soil and soil fertility is;

  • the types of fertilizers and what their role is;

  • how to plan and carry out the testing of selected soil properties and the impact of soil constituents on plant development.

You will learn
  • to define the terms of soil degradation and devastation

  • to list and discuss the sources and types of soil pollutants

  • to discuss, using examples, the harmful effects of selected chemical pollutants of soil (heavy metals, hydrocarbons, pesticides, nitrates

  • to justify the relationship between the development of civilization and the existing soil pollution

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Nagrania abstraktu przedstawiające różne typy dokonywania oprysków.

Soil pollution

Soils, like the entire natural environment, may become polluted. Due to their sorptive properties, soils absorb a lot of chemical substances that penetrate into them in the form of:

  • solids – ashes, plastics;

  • liquids – wastewater discharged into water reservoirs and entering soil together with water;

  • gases – harmful gases absorbed by the soil or first dissolved by water, and then entering soil together with water;

We talk about soil pollution when chemical substances occur in it in quantities exceeding their typical content and cause changes in soil properties that do not allow for its normal use.

The main sources of soil pollution caused by human activity:

  • industrial – mining, energy, metallurgical, steel, chemical, construction industry;

  • agricultural – too intensive fertilization, excessive use of pesticides;

  • municipal – sewage and solid waste;

  • communication – toxic substances and heavy metals contained in the vehicle exhaust, salt, which is sprinkled on ice‑covered road surfaces.

Source of pollution

Types of pollutants

industry

dust and smoke (containing, among others, heavy metals – lead, mercury, cadmium, poisonous chemicals), heaps

gases – carbon oxides and nitrogen oxides

wastewater and post‑production waste

agriculture

pesticides

fertilizers and their impurities

transport

car fumes – nitrogen oxides, carbon oxides

hydrocarbons

salt

households

packaging

sewage (including detergents)

Pesticides

PesticidespesticidesPesticides are chemical compounds used, among others, for:

  • plant protection against pests (insecticides) and fungi (fungicides),

  • plant disease control (bactericides),

  • weed removal (herbicidesherbicidesherbicides).

Pesticides spread in the environment through air and water, but they also remain in the soil. Due to the their exceptionally long shelf‑life, toxicity and high biological activity, pesticides pose a serious threat to the natural environment.

Pollutants of petroleum origin

When the significant amounts of hydrocarbons which originate, among others, from petroleum and the products of its processing, i.e. gasoline, diesel oil, get into the soil, they can cause its exclusion from biological activity for the period of 10 -15 years. Soil supersaturation with these products destroys soil and plant microorganisms and causes oxygen deficiency.

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The causes of soil pollution with petroleum substances may be failures at petrol stations, such as unsealing of fuel installations or road tankers (spillage of fuel, emission of hydrocarbon vapors into the air)
Source: Sdi-jr, licencja: CC BY 3.0.

Inorganic salts

An excess of nitrates in the soil reduces the resistance of plants to diseases and pests. Overfertilization of plants may be the cause of their physiological diseases. High‑grade mineral fertilizers used in excessive amounts may in many cases be more harmful than a shortage of nutrients in the soil. The plants grown in the soil contaminated with nitrates may also be harmful to consumers. In certain conditions, nitrates accumulated in the tissues of plants may undergo conversion to nitrites, which have carcinogenic properties (they promote cancer development).

Task 1

Formulate a research question and hypothesis before doing the experiment “Testing the presence of nitrites in vegetables”

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Zapisz swoje obserwacje i wnioski.
Experiment 1

Testing the presence of nitrates in vegetables.

You will need
  • test tubes,

  • Petri dishes or watchglasses,

  • pipette,

  • root vegetables, e.g. carrot, parsley, beetroot, radish and potato (from different cultivations),

  • indicator strips for detecting nitrates and nitrites,

  • Rivanol solution (dissolve 1 tablet in 20 cmIndeks górny 3 of distilled water),

  • hydrochloric acid, 5%,

  • magnesium chips.

Instruction
  1. Prepare small pieces of peeled vegetables and place them on watchglasses.

  2. Carry out, one by one, tests for the presence of nitrates; to this aim: apply 2–3 drops of Rivanol solution on a vegetable sample, add 2–3 drops of hydrochloric acid, watch the color; if a pinkish‑red color appears around the place on the sample where liquid was applied, confirming the high amount of nitrates, end the test; if such a color does not occur, sprinkle the sample with magnesium chips and observe changes in colour – nitrite ions will cause the sample to turn red and nitrate ions  – to light violet.

  3. You can also perform a test for nitrate and nitrite ion concentration using test strips. Follow the instructions on the packaging.

Summary
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Zapisz swoje obserwacje i wnioski.

Nitrogen needed for plant growth is taken up by plants in the nitrate NO3- or ammonium form NH4+. However, it may also occur in the soil in the form of nitrites which are toxic to many plants. Not all vegetables accumulate nitrates and nitrites equally. These compounds are accumulated to a high extent by, for example: radish, beets, parsley, to a lesser extent – carrot, celery, potato and onion.

This pollution may lead to a significant reduction in plant resistance to diseases and pests. Plants grown in soils polluted with nitrates and nitrites contain an excess of these substances and have a negative impact on the health of consumers. Excess nitrates can be converted to nitrites, which contribute to the formation of very toxic compounds exerting carcinogenic activity. Processes of this type may occur, for example, when storing vegetables containing excessive amounts of nitrates.

Task 2

Formulate a research question and hypothesis before doing the experiment “Testing the effect of soil salinity on plant growth”

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Zapisz swoje obserwacje i wnioski.
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In trees in street belts, you can often observe the effects of soil salinity, which is caused by the salt spraying of icy roads in the winter season.
Experiment 2
Research problem

Does soil salinity affect the development of plants?

Hypothesis

Excessive concentration of sodium chloride in the soil has a negative effect on plant development.

You will need
  • 4 measuring cylinders (100 cmIndeks górny 3) or 4 test tubes,

  • marker,

  • dropper,

  • saline solutions 1%, 5%, 10%,

  • tap water,

  • edible oil,

  • 4 stems of lilac or hazel with well developed leaves (or 4 shoots of spiderwort).

Instruction
  1. Pour the same amount (80 cmIndeks górny 3) of saline solutions to 3 cylinders and pour water to the fourth cylinder. Make sure that each cylinder is labeled with the information about its content.

  2. Place one shoot in each cylinder, then pour the edible oil in a quantity sufficient to form a 5 mm thick layer; this will prevent water vaporization. Mark the initial liquid level in the cylinders.

  3. Leave samples for 2–3 days. Observe the occurring changes.

Summary
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Zapisz swoje obserwacje i wnioski.

Excessive concentration of salt in the soil solution makes it difficult or impossible for the plants to take up water. The degree of salinity depends on the amount of water in the soil. The negative reaction of plants to excess salt is their wilting, and at higher concentrations – dieback (halophytes are an exception). Salinity is caused by: chlorides, sulfates, sodium and potassium carbonates.
The effects of excessive salinity in Poland may be observed on the leaves of roadside trees in June and July.

Heavy metals

Heavy metals – lead Pb, copper Cu, mercury Hg, cadmium Cd – are another group of the chemical pollutants of soil. Over 90% of the total content of cadmium, copper, zinc and lead in soils comes from anthropogenic sources. A particularly high content of heavy metals in the soil was found in the areas adjacent to steel mills, galvanizing plants and mines.
Heavy metals polluting the soil accumulate in the tissues of plants and cause irreversible changes in their organisms. They are also toxic to consumers (they can cause many diseases, including cancer).

Experiment 3

Detection of lead(II) ions in soil.

You will need
  • test tubes,

  • filter papers,

  • conical flasks,

  • spoon,

  • pipette,

  • funnels,

  • acetic acid,

  • sodium sulfide,

  • soil samples (taken in various sites).

Instruction
  1. Pour about 150 cmIndeks górny 3 of distilled water into the conical flask and add 2 cmIndeks górny 3 of acetic acid.

  2. Add a tablespoon of the tested soil to the solution, stir it, and shake for about 5 minutes.

  3. Filter the contents of the flask.

  4. Add 2 drops of sodium sulfide solution to the solution obtained. Observe the occurring changes.

  5. Similarly, test other soil samples.

Summary
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Zapisz swoje obserwacje i wnioski.
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Soil pollution with heavy metals in Poland
Source: GroMar Sp. z o.o., licencja: CC BY-SA 3.0.
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Exercise 1
Select true statements. Możliwe odpowiedzi: 1. Soils most contaminated with heavy metals are found in Upper Silesia, 2. Plants need nitrogen to grow, so the residues of nitrites in vegetables, regardless of their amount, are harmless to humans, 3. The source of soil pollution with fertilizers and pesticides is industry, 4. Heavy metals contribute to the development of cancer diseases in humans

Summary

  • The chemical sources of soil pollution include, among others, hydrocarbons and their derivatives, chemical fertilizers, pesticides, heavy metals.

  • Contaminated soil is unsuitable for cultivation as harmful substances enter the consumer's organisms along with the plants grown.

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Grafika przedstawiająca tablicę szkolną, na której znajdują się zdania do dokończenia. Finish selected sentences. 1 It was easy for me (uzupełnij). 2 It was difficult for me (uzupełnij). 3 Today I learned (uzupełnij). 4 I understood that (uzupełnij). 5 It surprised me (uzupełnij).
Source: GroMar Sp. z o.o., licencja: CC BY-SA 3.0.

Keywords

herbicides, pesticides

Glossary

herbicides
herbicides
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Nagranie dźwiękowe słówka: herbicides

herbicydy – rodzaj pestycydów, które służą ochronie upraw przed chwastami

pesticides
pesticides
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Nagranie dźwiękowe słówka: pesticides

pestycydy – chemiczne środki ochrony roślin uprawnych przed organizmami szkodliwymi lub niepożądanymi, szczególnym ich rodzajem są używane do zwalczania owadów insektycydy