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Exergonic and endoenergetic reactions – oxidation and combustion

Burning wood
Source: domena publiczna.

Link to the lesson

Before you start you should know
  • that the substances involved in the chemical reaction are substrates and the substances obtained as a result thereof are products;

  • the course of chemical reactions is recorded using equations, symbols of elements and formulas of chemical compounds;

  • digits placed in front of symbols of elements and formulas of chemical compounds in the equations of chemical reaction are stoichiometric coefficients;

  • chemical reactions can be divided into synthesis, analysis and exchange reactions.

You will learn
  • what kind of effects may accompany chemical reactions;

  • differences between combustion and oxidation;

  • to list examples of combustion and oxidation from everyday life and the human environment;

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nagranie dźwiękowe abstraktu

What effects can accompany chemical reactions?

All chemical reactions are accompanied by an energy effect. Under this concept, we mean the emission of energy into the environment or its uptake by reacting substances. During the conversion of substrates into products, the system may give energy in various forms to the environment – in the form of heat, light, work or even electricity. The same type of energy during other chemical changes can be absorbed by reacting substrates. Whether energy will be released during the reaction or whether energy is consumed depends on the substances reacting with each other.

Task 1

Before you watch the movie „Combustion of magnesium in oxygen”, formulate a research question and a hypothesis. Write down the observations and conclusions.

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Nagranie filmowe przedstawia doświadczenie - spalanie magnezu w powietrzu. Użytkownik pobiera próbkę magnezu i podstawia ją pod płomień palnika kuchenki gazowej. Magnez zaczyna płonąć jasnym mocnym płomieniem.
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Analysis of the experiment: "Combustion of magnesium in oxygen”. Research question (Uzupełnij). Hypothesis (Uzupełnij). Observations (Uzupełnij). Conclusions (Uzupełnij).

It may be surprising that regardless of whether substances react with one another or emit energy, each chemical conversion requires a certain amount of energy, without which it cannot be initiated. Before using the heat released during the reaction of carbon with oxygen (coal burning), you need to provide the substrate with the right amount of energy. After initiation, the reaction (combustion) proceeds spontaneously. This is also the case when motor vehicles move. Neither petrol nor diesel fuel is immediately ignited in the presence of oxygen from the air. What is needed is an additional factor (energy) that would initiate this reaction. In gasoline engines it is an electric spark, while in diesel engines – compression (volume reduction) and fuel heating. These impulses initiate the reaction of fuel with oxygen, which occurs with the release of energy.

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During the fireworks display a fuse is fired which will provide the energy needed to initiate the reaction between components of the pyrotechnic mixture
Source: bitslammer, licencja: CC BY-SA 2.0.

All reactions differ in the amount of energy required to initiate them. There are changes that only a small amount of energy is needed to initiate, such as a slight shock, as in the case of substances contained in explosives. Some, however, need more energy to initiate the conversion of substrates into products.

What is the difference between oxidation and combustion?

During oxidation, the atom passes from a lower level of oxidation to a higher one (which is equivalent to electron donation). In practice, a given reaction is called oxidation when the increase in the oxidation state concerns a compound or chemical element being the main subject of the reaction. This name is contractual since each oxidation reaction must be accompanied by a reduction reaction. In total, this process is called the redox reaction. As a electron acceptor, a chemical compound (oxidizer) or a positive electrode (anode) may be used. The process of combining substances with oxygen can occur slowly. An example of such a process is the oxidation of iron to iron(III) oxide, which is the main component of rust: steel or iron parts of various objects rust gradually, with no visible energy effects.

 Combining the substance with oxygen can also take place very quickly, with the release of energy in the form of a large amount of heat and light. In this case, combustion occurs. The Combustion reactioncombustion reactionCombustion reaction is a reaction with oxygen, that proceeds relatively quickly, in a rapid manner; it is accompanied by thermal, light and sometimes even sound effects. Combustion takes place when the entire mass of the combusted substance is oxidized. It occurs when not only there is no smoke or inflammable substances in the ash, but also some of the fuel in the form of steam does not escape.

Conclusion: combustion is also oxidation, while not every oxidation is combustion.

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Exercise 1
Analyse the reactions below. Indicate the combustion reactions and the others reactions. Reakcja pierwsza: es dodać o dwa strzałka w prawo es o dwa, reakcja druga: cztery ef e dodać trzy o dwa strzałka w prawo dwa ef e dwa o trzy, reakcja trzecia: pe cztery dodać pięć o dwa strzałka w prawo pe cztery o dziesięć, reakcja czwarta: dwa es o dwa dodać o dwa strzałka w prawo dwa es o trzy, reakcja piąta: dwa ce u dodać o dwa strzałka w prawo dwa ce u o, reakcja szósta: dwa ha dwa dodać o dwa strzałka w prawo dwa ha dwa o
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Create a multiple-choice test based on today's lesson. Then exchange your questions with a friend or classmate.
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Exercise 2
Type of oxidation reaction, which consists in the rapid connection of the substance with oxygen, which is often accompanied by effects: light, thermal, and sometimes sound is called: Możliwe odpowiedzi: 1. combustion reaction, 2. evaporation, 3. analysis reaction
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Exercise 3
Complete the reaction equation. Dostępne opcje do wyboru: ha dwa o, o trzy, trzy, dwa, em gie o. Reakcja: (tu uzupełnij) em gie dodać o dwa strzałka w prawo dwa (tu uzupełnij).
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Exercise 4
Complete the reaction equation:
Dostępne opcje do wyboru: 2, 6, 3, 4. Polecenie:(tu uzupełnij) a el dodać trzy o dwa strzałka w prawo (tu uzupełnij) e el dwa o trzy
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Exercise 5
Complete the reaction equation:
Dostępne opcje do wyboru: 4, ce o dwa, 3, ce o, 2. Reakcja: (tu uzupełnij) ce dodać o dwa strzałka w prawo dwa (tu uzupełnij)
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Exercise 6
Complete the reaction. Dostępne opcje do wyboru: 2, 2, 4, 3. Reakcja: uzupełnij ce o dodać o dwa strzałka w prawo uzupełnij ce o dwa
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Exercise 7
Complete the reaction equation:
 Dostępne opcje do wyboru: 5, 2, 3. Reakcja: pe cztery dodać (tu uzupełnij) o dwa strzałka w prawo pe cztery o dziesięć
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Exercise 8
Complete the reaction equation:
Dostępne opcje do wyboru: 4, 3, 5, 2. Reakcja: (tu uzupełnij) ef e dodać (tu uzupełnij) o dwa strzałka w prawo (tu uzupełnij) ef e dwa o trzy.
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Exercise 9
Complete the reaction equation:
Dostępne opcje do wyboru: es, es o dwa, 4, 2. Polecenie: 2 (tu uzupełnij) dodać o 2 strzałka w prawo (tu uzupełnij) es o trzy
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Exercise 10
Complete the reaction equation:
Dostępne opcje do wyboru: 5, 3, 2, 4. Reakcja: dwa en dwa dodać (tu uzupełnij) o dwa strzałka w prawo (tu uzupełnij) en dwa o pięć
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Exercise 11
Complete the reaction. Dostępne opcje do wyboru: 2, 4, 2, 3. Reakcja: uzupełnij be a dodać o dwa strzałka w prawo uzupełnij be a o

Summary

  • All chemical reactions, in order to start, require a certain amount of energy. Every chemical change needs a different amount of this energy.

  • Due to energy effects, we divide chemical reactions into exergonic and endoenergetic.

  • Exergonic reactions are chemical changes during which energy from the reaction system is released into the environment in the form of heat, light or work.

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Grafika przedstawiająca tablicę szkolną, na której znajdują się zdania do dokończenia. Finish selected sentences. 1 It was easy for me (uzupełnij). 2 It was difficult for me (uzupełnij). 3 Today I learned (uzupełnij). 4 I understood that (uzupełnij). 5 It surprised me (uzupełnij).
Source: GroMar Sp. z o.o., licencja: CC BY-SA 3.0.
Homework
Task 2.1

Conversion of food in the human body are endoenergetic reactions. Find information on the amount of energy that can be obtained from combustion of specific weight (100 g) of nutrients: carbohydrates, proteins and fats. Evaluate which food provides the largest amount of energy?

Keywords

Combustion reaction

Glossary

combustion reaction
combustion reaction
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Nagranie dźwiękowe słówka.

reakcja spalania – rodzaj reakcji utleniania, która polega na gwałtownym łączeniu się substancji z tlenem, czemu często towarzyszą efekty: świetlny, cieplny, a czasem dźwiękowy